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JH Valley,
If you're referring to the "Window Color and Appearance" option, you first need to have the Windows Aero theme selected. Anything except the Aero theme will default you to the classic appearance properties window, which you see above. However, from your screen shot above, it looks like you are running Vista Basic? If that's the case, then click the "Advanced..." button and you can manually adjust the colors for each window element. Not the most ideal way of doing things, but it works.
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